You would just melt the chocolate and then dip the strawberries to layer in your mold. Make sure your strawberries are dry before dipping. You could also coat the inside of your mold to get more of a "casing" on the outside - at least at the bottom of the mold which will become the top of the cake when you unmold it.
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Ooops! Meg posted about this cake when she made but the link never made it over here to the photo. Here is how she assembled it.
Hand dipped chocolate covered berries, piled into a silicone bundt mold. It's this shape basically because that was the only silicone mold I could find on my shelf (and I KNOW I have others -- or I'd swear I did -- that weren't cupcake size ones). It turned out well. Next time, I think I'd do a layer of chocolate on the bottom (top?) of the cake pan, so that you get the design all the way around. I didn't think about design - I was just thinking more of the ridges would hold the berries closer. There were a few "loose" spots, so once the whole thing was cold and unmolded (the silicone was helpful because I could just peel it off), I took a little more chocolate and piped it in the cracks - kinda like pointing brick - and used a little more to glue down the candle. It did fall apart a little while slicing, but nobody complained and people were impressed it was sliceable. (Serrated knife.) I think because I was afraid of OVER-chocolating, and was a little skimpy in some spots.
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